Revisiting Tracer Liu-Silva-Macedo model for binary diffusion coefficient using the largest database of liquid and supercritical systems
The Journal of Supercritical Fluids(2021)
摘要
•Tracer diffusion coefficients (D12) of liquid and supercritical (SC) systems.•Compilation of the largest D12 database: 6180 experimental points and 331 systems.•Revisiting Tracer Liu − Silva − Macedo (TLSM) model and its 1-parameter correlations.•Comparison with hydrodynamic, free-volume and LJ models from the literature.•TLSM model and its correlations are the most reliable for both liquid and SC fluids.
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关键词
Tracer diffusion coefficients,Modeling,Prediction,Correlation,Supercritical fluids,Liquids
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