Syntheses, crystal structures and photocatalytic properties of homometallic and heterometallic titanium-oxo clusters

Xin Li,Yi Zhu,Yanli Gai,Yuwen Shi,Tingyu Wei,Yating Wang,Aling Zhou,Hui Zhang,Huan Wang,Kecai Xiong

Inorganic Chemistry Communications（2021）

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摘要

Two titanium-oxo clusters have been synthesized and characterized. 1 features a Ti6 core, while 2 possesses a heterometallic Ti4Zn8 core. Notably, compounds 1 and 2 exhibit much higher and more efficient photocatalytic degradation abilities for rhodamine B than TiO2 under visible light irradiation.

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关键词

Titanium-oxo cluster,Carboxylic ligand,Crystal structure,Rhodamine B,Photocatalytic property

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