Boosting the Performance of Nano-Ni Catalysts by Palladium Doping in Flow Hydrogenation of Sulcatone

The effect of Pd doping on nano-Ni catalyst hydrogenation aptitude in sulcatone (6-methyl-5-hepten-2-one) hydrogenation was investigated. Obtained results demonstrated that the addition of non-catalytic amounts of Pd to the surface of parent Ni catalyst improves the activity to the extent that it surpassed the activity of 2.16 wt% Pd catalyst (model catalyst) at optimal reaction conditions in the flow hydrogenation of an unsaturated ketone. Pd doping improves hydrogen activation on the catalyst, which was found to be a rate-limiting step using kinetic isotopic measurements and theoretical calculations.