Catalytic Effect of Different Hydroxyl-Functionalised Ionic Liquids Together with Zn(II) Complex in the Synthesis of Cyclic Carbonates from CO2
MOLECULAR CATALYSIS(2021)
Abstract
•Several hydroxyl-functionalised quaternary ammonium salts were used as catalysts in the coupling reaction between CO2 and epoxides.•The effect of a hydroxy-isopropyl substituent was studied for the first time and revealed to have a positive effect in the reaction kinetics.•The best catalytic activity was attained when both effects (electrostatic and hydrogen bonding) were combined.
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Key words
CO2 utilization,epoxides,organic carbonates,propylene carbonate,ionic liquids,catalysis,arylhydrazones of B-diketones
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