Synthesis, Molecular Structure and Spectroscopic Studies of 6,6'-(1E,1'e)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(phenylmethan-1-yl-1-ylidene)bis(3-(octyloxy)phenol)
Crystallography Reports(2020)
摘要
6,6'-(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-ylidene))bis(phenylmethan-1-yl-1-ylidene)bis(3-(octyloxy)phenol) has been synthesized and characterized by FTIR, 1H, 13C NMR and single-crystal X-ray determination. The compound crystallizes in monoclinic space group C2/c with Z = 4 in the unit cell. The asymmetric unit of the compound contains one half-organic molecule. The molecule is located about a two-fold rotation axis which bisects the central C14-C14i bond. The dihedral angle between the phenyl rings is 68.46(11)°. In the crystal, intramolecular O–H⋅⋅⋅N hydrogen bonds generates a six-membered ring, producing an S(6) ring motif. The crystal packing is also stabilized by C–H⋅⋅⋅π interactions.
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关键词
Lanthanide Coordination Complexes
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