How Does the Number of Arms Affect the Properties of Mikto-Arm Stars in a Selective Oligomeric Matrix? Insights from Atomistic Simulations.

We present a simulation study of amphiphilic mikto-arm star copolymers in a selective polymer host. By means of atomistic molecular dynamics simulations, we examine the structural and dynamical properties of mikto-arm stars with varying number, n, of poly(ethylene oxide) (PEO) and polystyrene (PS) arms, (PEO) n (PS) n in a 33% wt blend with an oligomeric PEO host (o-PEO). As the number of arms increases, the stars resemble more spherical particles with less separated PEO and PS intramolecular domains. As a result of their internal morphology and associated geometrical constraints, the mikto-arm stars self-assemble either into cylindrical-like objects or a percolated network with increasing n, within the o-PEO matrix. The segmental dynamics is mostly governed by the star architecture and the heterogeneous local environment, formed by the intra- and intermolecular nanosegregation. We discuss the role of each factor and compare the results with previously published studies on mikto-arm stars.