SEI Formation on Sodium Metal Electrodes in Superconcentrated Ionic Liquid Electrolytes and the Effect of Additive Water

We have previously reported that water addition (similar to 1000 ppm) to an N-methyl-N-propylpyrrolidinium bis(fluorosulfonyl)imide (C(3)mpyrFSI) superconcentrated ionic liquid electrolyte (50 mol % NaFSI) promoted the formation of a favorable solid electrolyte interphase (SEI) and resulted in enhanced cycling stability. This study reports the characterization of Na-metal anode surfaces cycled with these electrolytes containing different water concentrations (up to 5000 ppm). Morphological and spectroscopic characterization showed that water addition greatly influences the formation of the SEI and that , similar to 1000 ppm of water promoted the formation of an active and more uniform deposit, with larger quantities of SEI species (S, O, F, and N) present. Water addition to the electrolyte system is also proposed to promote the formation of a new complex between the FSI anions, water molecules, and sodium cations as components of the SEI. For both dry and wet (similar to 1000 ppm) electrolytes, the SEIs were mainly composed of NaF, metal oxide (i.e., Na2O), and the complex, suggested to be Na-2[SO3-N-SO2F]center dot nH(2)O (n = 0-2). Postcyding SEM analysis of the Na-metal electrodes after extensive cycling (500 cycles, 1.0 mA.cm(-2), 1.0 mA.cm(-2)) was used to estimate the minimal average cycling efficiency (ACE), which was enhanced by water addition: up to similar to 99% for the 1000 ppm cell compared to similar to 98% for the dry cell. Two distinct deposit morphologies, a microporous and a compact layer deposit, were evident after extended cycling in the wet and dry electrolytes. The presence of both the microporous and compact layer deposits on Na-metal surfaces cycled with the wet electrolyte, along with the distinct chemistry and morphology of the SEI, all contributed to a more stable symmetric cell voltage profile and lower cell polarization. In contrast, a higher fraction of microporous deposits and the absence of compact layer formation in the dry electrolyte were associated with higher cell polarization potentials and the occurrence of dendrites.