Kinetic Model For Electron-Ion Transport In Warm Dense Matter

We present a model for electron-ion transport in warm dense matter that incorporates Coulomb coupling effects into the quantum Boltzmann equation of Uehling and Uhlenbeck through the use of a statistical potential of mean force. Although the model presented here can be derived rigorously in the classical limit [S. D. Baalrud and J. Daligault, Phys. Plasmas 26, 082106 (2019)], its quantum generalization is complicated by the uncertainty principle. Here we apply an existing model for the potential of mean force based on the quantum Ornstein-Zernike equation coupled with an average-atom model [C. E. Starrett, High Energy Density Phys. 25, 8 (2017)]. This potential contains correlations due to both Coulomb coupling and exchange, and the collision kernel of the kinetic theory enforces Pauli blocking while allowing for electron diffraction and large-angle collisions. We use the Uehling-Uhlenbeck equation to predict the momentum and temperature relaxation times and electrical conductivity of solid density aluminum plasma based on electron-ion collisions. We present results for density and temperature conditions that span the transition from classical weakly-coupled plasma to degenerate moderately-coupled plasma. Our findings agree well with recent quantum molecular dynamics simulations.