Double Insertion Of Co2 Into An Al-Te Multiple Bond

Matthew J Evans,Mathew D Anker,Claire L McMullin,Nasir A Rajabi,Martyn P Coles

CHEMICAL COMMUNICATIONS（2021）

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摘要

We report the [Al(NONDipp)(Te)(THF)](-) anion containing a terminal aluminium telluride bond. DFT calculations confirm appreciable Al-Te multiple bond character and reaction with CO2 proceeds via a double insertion to afford the previously unknown tellurodicarbonate ligand.

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