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Acid-triggering of Light-Induced Charge-Separation in Hybrid Organic/inorganic Molecular Photoactive Dyads for Harnessing Solar Energy

Inorganic chemistry frontiers(2021)

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摘要
H+modulated charge-transfer in photoexcited covalently linked W and Mo Keggin-bodipy conjugates is demonstrated using transient absorption spectroscopy and photoluminescence. Adding acid switches on (W) or accelerates (Mo) charge separation.
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