Palladium-Catalyzed Allylic Alkylation Reaction Of Alpha-Substituted Benzyl Nitriles With Branched Allyl Carbonates

Gaopeng Zhang,Yangjie Jiang,Changhua Ding,Xuelong Hou

Chinese Journal of Organic Chemistry（2020）

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摘要

Pd-catalyzed allylic alkylation reaction of alpha-substituted benzyl nitriles with branched allyl carbonates in the presence of bulkier N-heterocyclic carbene ligand was reported, which provided the corresponding allylated products in good yield with high regio- and diastereo-selectivity.

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关键词

palladium, benzyl nitriles, branched allyl carbonates, allylic alkylation reaction

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