Effect of MgF 2 Surface Modification for LiNi 0.8 Co 0.15 Al 0.05 O 2 Cathode Material on Improving Electrochemical Characteristics
Korean Journal of Chemical Engineering(2020)
摘要
Electrochemical characterization and thermal stability were investigated for MgF2 coated LiNi0.8Co0.15Al0.05O2 cathode. The ratio of MgF2 was controlled by 0.5, 1, 3 wt%. Cyclic voltammetty, charge-discharge profiles, rate capability, cycle life were measured for electrochemical properties. DSC analysis was measured for thermal stability. The first discharge capacities of MgF2 coated LiNi0.8Co0.15Al0.05O2 were decreased at 0.1C-rate compared to pristine LLiNi0.8Co0.15Al0.05O2. But the rate capability and cycle life of MgF2 coated LiNi0.8Co0.15Al0.05O2 were improved at 2C-rate. In DSC analysis result, the exothermic temperature of MgF2 coated LiNi0.8Co0.15Al0.05O2 was increased and peak height was decreased.
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关键词
Lithium secondary battery, Cathode material, LiNi0.8Co0.15Al0.05O2, MgF2 coating, Thermal stability
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