Nickel-Catalyzed Alpha-1,3-Dienylation Of 1,3-Dicarbonyl Compounds With Propargylic Carbonates

Naoki Ishida,Yuka Kamino,Masahiro Murakami

Synlett（2021）

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摘要

Herein reported is a nickel-catalyzed alpha-1,3-dienylation reaction of 1,3-dicarbonyl compounds with substituted propargylic (e.g., but-2-ynyl) carbonates. The propargyl unit changes into a 1,3-dienyl unit, which is incorporated at the alpha-position of the 1,3-dicarbonyl compounds.

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关键词

nickel, 1,3-diene, malonate, propargylic carbonate, C-C bond formation

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