A Non-Isolated Pentagon Rule C-82 Cage Stabilized By A Stretched Sc3n Cluster Dagger

Min Guo,Xiaomeng Li,Yang-Rong Yao,Jiaxin Zhuang,Qingyu Meng,Yingjing Yan,Xinye Liu,Ning Chen

CHEMICAL COMMUNICATIONS（2021）

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摘要

A novel cluster fullerene, Sc3N@C-s(39 663)-C-82, has been synthesized and characterized. Crystallograpic charaterization unambiguously determines the non-IPR cage structure of C-s(39 663)-C-82. Structural analyses further reveal that the Sc3N cluster is notably stretched to facilitate the interaction with the non-IPR fullerene cage.

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