Coordination Capacity of Keggin Anions As Polytopic Ligands: Case Study of [Vnb12o40]15.

Anna A. Mukhacheva,Victoria V. Volcheck,Dmitry G. Sheven,Vadim V. Yanshole,Nikolay B. Kompankov,Mohamed Haouas,Pavel A. Abramov,Maxim N. Sokolov

Dalton transactions（2021）

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摘要

[VNb12O40]15− polytopic ligand can coordinate to up to five {(C6H6)Ru}2+ groups. Combined analytical separation tools together with 1H DOSY NMR were firstly applied to the solution studies of polyoxoniobate based complexes.

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