Facile and Selective Conversion of Levulinic Acid into γ-Valerolactone by Low-cost Fe and Ni Catalysts in Water
ChemRxiv(2021)
摘要
Renewable chemical production from biomass
is desirable for the sustainable development of the society. Levulinic acid
(LA) is a common biomass-derived building block that furnishes a suitable
source to produce the industrially valuable γ-valerolactone (GVL). In this
work, a low-cost, green and effective catalytic system was developed to
transform LA into GVL in water by using Fe and Ni, in which the hydrogen source
was provided by water splitting. The Fe primarily functioned as the reductant
that transformed into Fe3O4 species after the reaction,
while Ni played the major catalytic role to promote selective LA hydrogenation
into GVL. After optimizations, the GVL yield reached the highest of 99% within
2-3 h at relatively low hydrothermal temperature of 230-250 °C. The recycling
tests of Ni has suggested negligible decrease of product yield after four runs.
This study establishes a green, facile and eco-friendly approach to synthesize
GVL from biomass-derived LA.
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