Unusual stereoselectivity of methionine-γ-lyase from Citrobacterfreundii toward diastereomeric (S)-methionine S-oxide

Nikolai G. Faleev,Marina A. Tsvetikova,Mikhail M. Ilyin, Vyacheslav S. Yufryakov,Natal’ya G. Kolotyrkina, Viktoria V. Kulikova, Tatiana V. Demidkina,Konstantin A. Kochetkov

Mendeleev Communications（2021）

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摘要

Using a diastereomeric mixture of (S)-methionine S-oxide as an example, kinetic preference of methionine-γ-lyase toward a stereogenic center at the γ-sulfur atom of the (2S, RS) diastereomer was discovered for the first time.

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关键词

methionine-γ-lyase,stereoselectivity,kinetic resolution,diastereomers,(S)-methionine S-oxide

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