Copper carbene complexes. Synthesis and structural analysis of a chloro-bridged dicopper cation and the triosmium-copper carbene cluster complex HOs3(CO)11[µ-Cu(IPr)]

Richard D. Adams,Mark D. Smith,Jonathan D. Tedder,Nutan D. Wakdikar

Journal of Organometallic Chemistry（2021）

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摘要

•A triosmium carbonyl cluster with a bridging Cu(IPr) group on one edge of the cluster and a terminally-coordinated hydrido ligand.•A carbene-substituted dicopper cation with a bridging chloro ligand.

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关键词

Copper,N-Heterocyclic carbene,Osmium,Cluster,Bimetallic

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