Rational Molecular Design Of Azaacene-Based Narrowband Green-Emitting Fluorophores: Modulation Of Spectral Bandwidth And Vibronic Transitions

ACS APPLIED MATERIALS & INTERFACES(2021)

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摘要
A series of green-emitting fluorophores based on a tetra-azaacene core is synthesized by introducing nitrile substituents at different positions. Their molecular structure-optical property relationship [i.e., vibronic transitions in photoluminescence (PL) and electroluminescence (EL) spectra] is investigated to obtain a sharp emission where the vibronic peak v(0-0) should be intensified by suppressing v(0-n) (n = 1, 2, 3...) transitions. The intensity ratios (I0-1/I0-0) of the v(0-1) and v(0-0) vibronic transitions in the PL spectra of DBBNP, DBBNP2CN1, and DBBNP2CN2 in hexane are 1.13, 0.80, and 0.67, respectively. Theoretical calculations explain that the CN substitution at positions 8 and 13 in DBBNP2CN2 induces a uniform charge distribution and reduces the Huang-Rhys factors (HRFs) of the vibrational normal modes coupled to the electronic transition. The organic light-emitting diode (OLED) fabricated with DBBNP2CN2 shows a narrower green EL emission at 518 nm with a smaller bandwidth (50 nm) than those of devices adopting DBBNP or DBBNP2CN1. The careful modification of the molecular structures and positions of substituents enables us to reduce the HRFs of vibrations to achieve a narrow emission bandwidth with decreased I0-1/I0-0, which suggests a design strategy to develop narrowband organic fluorophores to improve the color purity for wide-gamut OLED displays.
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关键词
organic fluorophores, OLEDs, azaacene, narrow bandwidth, vibronic transition
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