Bimetallic Aluminum Complexes Bearing Novel Spiro-Phenanthrene-Monoketone/Oh Derivatives: Synthesis, Characterization And The Ring-Opening Polymerization Of Epsilon-Caprolactone

A series of spiro-phenanthrene-monoketone/OH derivatives (L1-L6) were synthesized and fully characterized with H-1/C-13 NMR spectroscopy and elemental analyses. By treating ligands with AlMe3, oxygen-bridged binuclear aluminum complexes (Al1-Al6) were isolated and characterized by H-1/C-13 NMR spectroscopy. The molecular structures of ligands (L2, L4 and L5) and complex Al1 were determined by single crystal X-ray diffraction. In the presence of benzyl alcohol (BnOH), these aluminum complexes demonstrated high efficiency towards the ring-opening polymerization of epsilon-caprolactone (epsilon-CL), resulting in PCL in a linear manner with the BnO-end group. In addition, complexes Al1 and Al5 exhibited good catalytic activities even without BnOH. Moreover, complexes Al3 and Al6 with the bulkier substituent of Pr-i at the ortho-position of the arylamines demonstrated better catalytic activities than the analogs. Moreover, substituents on the backbone also affected catalytic behaviors.