Arylation of Gem-Difluoroalkenes Using a Pd/Cu Co-catalytic System That Avoids Β-Fluoride Elimination.

Kedong Yuan,Taisiia Feoktistova,Paul Ha-Yeon Cheong,Ryan A. Altman

Chemical science（2021）

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摘要

PdII/CuIco-catalyze a desulfitative arylation of aliphaticgem-difluoroalkenes in a radical arylation/migratory insertion sequence that avoids β-F elimination.

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