A Novel Narrow Band Blue-Emitting Phosphor Rb2zrsi3o9: Eu2+ With Low Thermal Quenching And High Quantum Efficiency
CERAMICS INTERNATIONAL(2021)
摘要
Developing phosphors with narrow band emission and excellent performance is the main goal of current leading research. In this study, a novel narrow band blue-emitting phosphor Rb2ZrSi3O9: Eu2+ was prepared that can be fully excited by near ultraviolet (NUV) light, emits a bright blue light peak at 470 nm, and has a full width at half maximum (FWHM) of 60 nm. The synthesized Rb2ZrSi3O9: Eu2+ had excellent photoluminescence properties that were reflected in its good thermal stability (up to 82%) and high internal quantum efficiency (up to 75%). These remarkable luminescence properties were mainly ascribed to the highly symmetric and dense crystal structure composed of [Si3O9](6-) ring pairs. Multiple emission centers in the Rb2ZrSi3O9: Eu2+ phosphor were confirmed through the photoluminescence (PL) spectra and time-resolved (PL) spectra. A bright warm WLED device with a low correlated color temperature (3386 K) and high color-rendering index (CRI similar to 89.3) was produced by combining the blue phosphor with (Sr, Ba)(2)SiO4: Eu2+ and CaAlSiN3: Eu2+ and NUV (380 nm). The results indicate that Rb2ZrSi3O9: Eu2+ could be a promising phosphor for use in WLEDs.
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关键词
LED, Blue phosphor, Narrow-band light-emitting, Silicate
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