After 200 Years: The Structure of Bleach and Characterization of Hypohalite Ions by Single-Crystal X-Ray Diffraction**
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION(2021)
摘要
We report the first X-ray single crystal structures of hypochlorite (ClO-) and hypobromite (BrO-) salts, including hydrated sodium hypochlorite, a staple of the chlorine industry and ubiquitous bleaching and disinfection agent for almost 200 years. The structures, supported by variable-temperature Raman spectroscopy on individual crystals and periodic density-functional theory (DFT) calculations, provide insight into solid-state geometry and supramolecular chemistry of hypohalite ions.
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关键词
bleach, halogens, hypobromite, hypochlorite, X-ray crystallography
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