Bis(2-Methylpyridinium) Tetrachloridocuprate(Ii): Synthesis, Structure And Hirshfeld Surface Analysis

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS(2021)

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摘要
The title compound, (C6H8N)(2)[CuCl4], crystallizes in the monoclinic space group I2/c. The coordination around the copper atom is a distorted tetrahedron. The 2-methylpyridinium ion (C6H8N+) interacts with the tetrachlorocuprate anion through N-H center dot center dot center dot Cl and C-H(phenyl)center dot center dot center dot Cl contacts, forming a hydrogen-bonded layer-like structure. The supramolecular structure is further stabilized by C-H(methyl)center dot center dot center dot Cl interactions between the layers.
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关键词
2-picoline complex, inorganic supramolecular chemistry, crystal structure, hydrogen bonding
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