A porous polyacrylonitrile (PAN)/covalent organic framework (COF) fibrous membrane photocatalyst for highly efficient and ultra-stable hydrogen evolution.

Photocatalytic water splitting has been regarded as one of the most promising technologies to generate hydrogen as an ideal energy carrier in the future. However, most of the experience for such process are derived from the researches based on the suspension powder photocatalysts under a stirring condition and a practical scaling application is urgently calling for the high-efficient panel reactors based on the membrane photocatalysts. Herein, we develop a new series of flexible and ultrastable membrane photocatalysts through a controllable growth of covalent organic framework (COF) photocatalysts on the polyacrylonitrile (PAN) electrospun fiber membrane. Multiple characterization techniques verify the successful anchoring of the COF-photocatalysts on the PAN fibers, forming a three-dimensional porous PAN/COF membrane photocatalyst with excellent light absorption ability, high specific surface area, and good hydrophily. As a result, the optimized PAN/COF membrane photocatalyst exhibits excellent hydrogen evolution rate up to 1.25 mmol gh under visible-light irradiation without stirring, which is even higher than that of the corresponding suspension COF-powder photocatalyst with stirring. In particular, the PAN/COF membrane photocatalyst demonstrates a much more superior hydrogen evolution stability and also a much better recyclability. This study gives some experience for the practical scaling application of solar-driven water splitting.