Enantioselective Gel Phase Synthesis of Metal-Organic Materials

Dipankar Ghosh,Marcin Górecki,Gennaro Pescitelli,Krishna Kumar Damodaran

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2021）

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摘要

We report the asymmetric synthesis of homochiral metal-organic materials (MOMs) in chiral gels from achiral components. The enantioselectivity of MOMs depends on the chirality of the gel, whereas the synthesis performed in solution phase and achiral gels resulted in conglomerates.

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关键词

chiral induction, enantioselective synthesis, metal-organic materials, solid-state CD, supramolecular gel phase synthesis

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