A Facile Approach to Prepare Silica Hybrid, Spin-Crossover Water-Soluble Nanoparticles As Potential Candidates for Thermally Responsive MRI Agents.

Patroula Gkolfi,Dimitra Tsivaka,Ioannis Tsougos,Katerina Vassiou,Ondrej Malina,Michaela Polaskova,Christina D. Polyzou,Christos T. Chasapis,Vassilis Tangoulis

Dalton transactions（2021）

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摘要

A reverse micelle method was used for the synthesis of water-soluble silica hybrid, spin-crossover (SCO) nanoparticles (NPs). MRI experiments provided temperature dependent T2 values, indicating their potential use as smart MRI agents, while lyophilization of NP dispersions in water yielded powders with a preserved but modified thermal hysteretic magnetic profile.

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