Nickel-Catalyzed Reductive Cross-Coupling Of Alkyl Bromides And Chlorosilanes
ORGANIC LETTERS(2021)
摘要
A novel nickel-catalyzed highly selective reductive cross-coupling of alkyl bromides and chlorosilanes to construct the C-Si bond has been developed. Under benign reaction conditions, a series of structurally interesting organosilanes can be accessed without Ni-catalyzed isomerization. The utility of this chemistry is illustrated by further transformations of the product. Moreover, the radical mechanism of the reaction is illustrated by control experiments.
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