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BaFe 12 O 19 -chitosan Schiff-base Ag (I) complexes embedded in carbon nanotube networks for high-performance electromagnetic materials

SCIENTIFIC REPORTS(2015)

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摘要
The multiwalled carbon nanotubes/BaFe 12 O 19 -chitosan (MCNTs/BF-CS) Schiff base Ag (I) complex composites were synthesized successfully by a chemical bonding method. The morphology and structures of the composites were characterized with electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction techniques. Their conductive properties were measured using a four-probe conductivity tester at room temperature and their magnetic properties were tested by a vibrating sample magnetometer. The results show that the BF-CS Schiff base Ag (I) complexes are embedded into MCNT networks. When the mass ratio of MCNTs and BF-CS Schiff base is 0.95:1, the conductivity, M s (saturation magnetization), M r (residual magnetization) and H c (coercivity) of the BF-CS Schiff base composites reach 1.908 S cm −1 , 28.20 emu g −1 , 16.66 emu g −1 and 3604.79 Oe, respectively. Finally, a possible magnetic mechanism of the composites has also been proposed.
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关键词
Environmental sciences,Materials chemistry,Science,Humanities and Social Sciences,multidisciplinary
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