Efficient Photocatalytic Water Oxidation Catalyzed By Polyoxometalate [Fe-11(H2o)(14)(Oh)(2)(W3o10)(2)-(Alpha-Sbw9o33)(6)](27-) Based On Abundant Metals

Xiaoqiang Du,Yong Ding,Fangyuan Song,Baochun Ma,Junwei Zhao,Jie Song

CHEMICAL COMMUNICATIONS（2015）

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摘要

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 +/- 50 and a turn-over frequency (TOFinitial) of 6.3 s(-1) over 1 were achieved for water oxidation.

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