Synthesis Of [Moos3cu3i(3, 5-Dimepy)(4)]Center Dot Ch3cn And (Et4n)(4)[Mo4cu8o4s12{(Ph2ps)(2)N}(4)] From Solid State Product [Et4n](4) [Mo2o2s6cu6i4br2]

Treatment of iodide-bridged dimer [NEt4] (4)[Mo2O2S6Cu6I4Br2] 1 With 3, 5-bimethylpyridine or with K[(Ph2PS) N-2] in CH3CN afforded the tetranuclear cluster [MoOS3Cu3I(3, 5-diMePy)(4)]. CH3CN 2 and dodecanuclear cluster (Et4N)(4)[Mo4Cu8O4S12((Ph2PS)ZN)4] 3 Monomeric 2 possess a nest- shaped skeleton. The structure of oligomeric 3 can be regarded as a tetramer of nest-shaped MoCu3OS3[(Ph2PS)(2)N] groups co-polymerized by sharing the limbic Cu atoms.