Z to E light-activated isomerization of α-pyridyl-N-arylnitrone ligands sensitized by rhenium(I) polypyridyl complexes

Julia F. Mamud, Giovanna Biazolla, Caroline S. Marques,Giselle Cerchiaro,Thiago B. De Queiroz,Artur F. Keppler,Andre S. Polo

Inorganica Chimica Acta（2021）

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摘要

•Rhenium polypyridyl compounds were prepared with α-pyridyl-N-arylnitrone ligands.•Z-E isomerization of the coordinated nitrones was done by 3ILZ-Nit photosensitization.•The 3MLCT lowest-lying excited state of the E-isomer formed enhances the emission.

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关键词

Photosensitized isomerization of nitrones,Rhenium(I) polypyridyl compounds,Photosensors

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