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Catalyst-free Valorization of Poly-3-hydroxybutyrate to Crotonic Acid

Reaction chemistry & engineering(2021)

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摘要
A novel catalyst-free valorization process of PHB to CA in inert nonpolar solvents is developed. CA was obtained with a yield of 89 wt% and a purity of 91% via a simple consecutive process of pyrolysis at 210 °C and vacuum distillation at 60 °C.
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