Undercoordinated Pb2+ Defects Passivation Via Tetramethoxysilane-Modified for Efficient and Stable Perovskite Solar Cells

Organic-inorganic hybrid perovskite solar cells (PSCs) have developed rapidly in recent years, and the instability limits its commercialization. Non-radiative recombination caused by defects and water stability affect the device stability. Here we introduce an organic silane additive, tetramethoxysilane (TMOS), which can reduce the nonradiative recombination and prevent the water erosion. The methoxy group in TMOS can combine with Pb2+ of perovskite to passivate undercoordinated Pb2+ defects and reduce non-radiative recombination. Under a certain humidity, the hydrolyzed product SiO2 can occupy the grain boundary sites to prevent the erosion of water molecules, slow down the degradation of perovskite, and improve the crystal phase stability of perovskite. The PCE of the device increases from 17.13% to 20.12%. After 400 h at 50% relative humidity (RH), the PSC with 2% TMOS can maintain the efficiency of 90%, while the efficiency of the control group quickly dropped to only 70% of the initial.