Synthesis, crystal structure of a novel metal–organic framework and its catalyzing properties on the selective oxidation of cyclohexene to cyclohexenone

Yong-Qiang Xie,You-Ming Zhang,Zhao-Hui Li,Hong Yao,Tai-Bao Wei,Bing-Bing Shi,Wen-Juan Qu,Qi Lin

Inorganica Chimica Acta（2021）

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摘要

A novel MOFs [Ni3(OABDC)2(bipy)3 (H2O)6]n(CH3OH)n(H2O)4.5n (1) was synthesized in this study by the hydrothermal method. The MOF 1 presented efficiency and selective catalytic performance for oxidizing cyclohexene into cyclohexenone using oxygen under heterogeneous conditions.

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关键词

3, 5-Dicarboxyphenoxyacetic acid,Nickel(II),Metal-organic frameworks,Oxygen,Oxidation of cyclohexene,Heterogeneous catalyst

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