Palladium Catalysts With Triglyme-Functionalized Nhc Ligands For Suzuki Coupling Reactions In Aqueous Solvent

CHEMISTRYSELECT(2021)

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摘要
To perform green chemistry, hydrophilic catalysts with high activity and stability are required. We designed and synthesized a catalyst [Pd(IPr*(TEG))(cin)Cl)] from commercially available materials; this catalyst could be used in a wide range of Suzuki coupling reactions in aqueous solvents. The reaction works smoothly under low catalyst loading with a good to excellent yield. It was noted that the catalyst can be recycled, and it performed well in cyclical reactions.
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关键词
Aqueous solvent, N-heterocyclic carbene, palladium, Suzuki coupling
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