Introducing a 4-pyridyl group on the backbone of polybenzoxazine to an analog fixed-DMAP catalyst

Tianfo Guo,Haoying Tong,Zhenjiang Li,Jie Sun,Yongqiang Li,Rui Yan,Bo Liu,Zhihao Zhang,Yuejia Zhu,Kai Guo

European Polymer Journal（2021）

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摘要

•Polybenzoxazine anchored pyridyl moiety as organocatalyst was firstly proposed.•The polybenzoxazine was evaluated as nucleophilic catalyst in acylation reaction.•The catalyst was comparable to commercial PS-DMAP in catalysis and in recycles.

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关键词

Acylation,Benzoxazine,Organocatalysis,Silylation,Tritylation

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