Lithium And Magnesium Phosphino- And Arsinoarylthiolates

Ana-Maria Valean,Santiago Gomez-Ruiz,Peter Loennecke,Luminita Silaghi-Dumitrescu,Evamarie Hey-Hawkins

REVUE ROUMAINE DE CHIMIE（2012）

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摘要

The molecular structure of 2-PPh2C6H4SH (PSH) and the preparation and structural characterization of the lithium and magnesium salts of 2-EPh2C6H4SH = P, As), [Li{(mu-SC6H4-2-PPh2)-kappa S}(TMEDA)](2) (1) (TMEDA = N,N,N',N'-tetramethylethylenediamine), Mg{(SC6H4-2-AsPh2)-kappa S}(2)(THE)(4) (2) and Mg{(SC6H4-2-PPh2)-kappa S-2,P}(2)(THF)(2) (3) are presented.

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关键词

lithium salt, magnesium complexes, monodentate vs. bidentate coordination, molecular structures

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