Absorption line asymmetry: Speed-dependent effects observed from coherent transients on the 86 GHz line of HC15N in collision with polar and diatomic molecules and with rare gases

Journal of Quantitative Spectroscopy and Radiative Transfer(2021)

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摘要
•Lineshape asymmetries: comparison of hypergeometric and quadratic SD-Voigt profiles.•HCN relaxation induced by polar and diatomic molecules and by rare gases.•Temperature dependence of broadening and frequency-shifting rates and of SD-parameters.•Consequences of e.m. field frequency instabilities on absorption lineshapes.•Lineshape analysis from time domain coherent transients (optical precession).
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关键词
HCN,Collisional relaxation,Lineshape asymmetry,Speed dependence,Temperature dependence,Millimeter wave coherent transients
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