On The Limiting Efficiency For Silicon Heterojunction Solar Cells

SOLAR ENERGY MATERIALS AND SOLAR CELLS(2021)

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摘要
Silicon heterojunction (SHJ) solar cell, as one of the promising technologies for next-generation passivating contact solar cells, employs an undiffused and n-type mono-crystalline silicon (c-Si) substrate and two amorphous-silicon-based selective contacts with opposite polarities. In this work, a numerical model based on Richter's theory has been developed to simulate the performances of a 25.11 % efficiency SHJ solar cell obtained recently. Analyses on series resistivity (R-s) explicit that the upper bound for the sum of contact resistivities for p-type (rho(c,p)) and n-type (rho(c,n)) contacts is 0.073 Omega cm(2). With the updated contact resistivities, the theoretical limiting efficiency estimated by Brendel's formulation is therefore 28.5 % for SHJ solar cells, which is comparable to 28.7 % for bi-facial tunneling-oxide passivating contact (TOPCon) solar cells. A hybrid structure consisting of p-type contact from SHJ and n-type contact from TOPCon is feasible to reach 28.9 % limiting efficiency in principle, showing potential of solar cells with hybrid structures.
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关键词
Silicon heterojunction, Selective contact, Contact resistivity, Theoretical limiting efficiency, Hybrid structure
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