Recent Progress On Supramolecular Luminescent Assemblies Based On Aurophilic Interactions In Solution

INORGANICS(2021)

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摘要
The development of supramolecular systems showing aurophilic interactions in solution is gaining much attention in the last years. This is due to the intriguing photophysical properties of gold(I) complexes, which usually confer to these supramolecular assemblies interesting luminescent properties, as well as the possibility of morphological modulation, through fine tuning of inter- and intramolecular aurophilic interactions, in synergy with the formation of other supramolecular contacts. In this work, an overview of the advances made in this area since 2015 is presented. A large variety of systems showing different spectroscopical and structural topologies has been reported. Moreover, these supramolecular assemblies have proven to be useful in a wide range of applications.
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关键词
gold(I) complexes, aggregation-induced emission, self-assembly, metallogelators, luminescent chemosensors, self-assembly modulation by cations and anions
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