Formation of the α''-phase and study of the solubility of Mn in Cd3As2

A. Ril',S. F. Marenkin,V. V. Volkov,L. N. Oveshnikov, V. V. Kozlov

Journal of Alloys and Compounds（2022）

引用 6|浏览8

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摘要

•Mn-doped Cd3As2 crystals were obtained from elemental and binary precursors.•Mn doping promotes structural transition into secondary polymorph modification.•At lower Mn content ternary Cd3−xMnxAs2 compound is formed.•Above solubility limit (x~0.13) the MnAs phase was detected.•The formation of CdAs2 phase in Cd3−xMnxAs2 + MnAs composites is suppressed.

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关键词

Phase diagram Cd-As,Cd3As2 system,Structural modifications of Cd3As2,Mn-doped Cd3As2,X-ray diffraction and thermal analysis of Cd3As2

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