On-Demand Electrochemical Synthesis of copper(I) Triflate and Its Application in the Aerobic Oxidation of Alcohols
semanticscholar(2021)
摘要
An on-demand electrochemical
synthesis of copper(I) triflate under both batch and continuous flow conditions
has been developed. A major benefit of the electrochemical methodology is that
the only by-product of the reaction is hydrogen gas which obviates the need for
work-up and purification, and water is not incorporated into the product. Upon
completion of the electrochemical synthesis, solutions are directly transferred
or dispensed into reaction mixtures for the catalytic oxidation of alcohols
with no requirement for work-up or purification.
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