Structure, optical and electro-physical properties of tetramerized anion-radical salt (N-Xy-Qn)(TCNQ)2

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy(2022)

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摘要
•TCNQ molecules in (N-Xy-Qn)(TCNQ)2 salt are organized in tetramerized stacks.•Charge disproportionation in TCNQ stacks is observed (−0.83 e vs −0.33 e).•Tetramerization and EMV coupling complicates the vibrational spectra.•The room temperature conductivity equals 2.6 mS cm−1.
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关键词
TCNQ,Charge transfer,Infrared,Raman,Conductivity,Tetramerization,EMV
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