Water binding to the atmospheric oxidation product methyl vinyl ketone

Carlos Cabezas,Marcos Juanes,Rizalina T. Saragi,Alberto Lesarri,Isabel Peña

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy（2022）

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摘要

•Four 1:1 complexes of methyl vinyl ketone − water identified.•Preference of water for an antiperiplanar conformation of methyl vinyl ketone.•Primary O − H···O and secondary C − H···O hydrogen bond interactions.•Threefold methyl internal rotation barrier heights determined.

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