Correlations between proton chemical shift tensors, deuterium quadrupole couplings, and bond distances for hydrogen bonds in solids
The Journal of Chemical Physics(1980)
摘要
Correlations between parameters characterizing the proton chemical shift tensors for O–H⋅⋅⋅O bonded protons in solids and O⋅⋅⋅O hydrogen bond distances and deuterium quadrupole coupling constants (e2qQ/h) are presented. The isotropic value of the chemical shift correlates very well with both RO⋅⋅⋅O and e2qQ/h, whereas the correlations involving the chemical shift anisotropy show much more scatter. A quantitative agreement is found with theoretical calculations performed by Ditchfield.
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