Radiative decay constants of the H2 Fulcher bands
The Journal of Chemical Physics(1978)
摘要
The radiative decay constants corresponding to the Fulcher bands of the H2 molecular spectrum are obtained using pulsed-electron beam techniques. Data in the range ∼1.8 to 2.8×107 s−1 are obtained at 25 eV incident electron energy for the d 3πu →a 3Σ+g (v′, v″) Q (K) and k 3πu →a 3Σ+g (v′,v″) Q (K) rotational lines with K=1,2,3 and v′=0,1,2,3,→v″=0,1,2,3. Additional measurements of the d 3πu→a 3Σg+(0,0) Q1 rotational line intensity indicate the presence of a two-mode decay over the energy range 50–300 eV. The long-lived decay component, identified as radiative cascade from upper levels, contributes ∼15% to the total d 3πu(v′=0) population.
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关键词
decay,constants
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