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Formation of New σ-Norbornenylrhodium(III) Complexes Promoted by Quinoline-8-carbaldehyde and Their Rearrangement into Nortricyclylrhodium(III) Derivatives. Formation of Norbornene and Nortricyclene

Organometallics(2011)

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摘要
[RhCl(Nbd)]2 (Nbd = norbornadiene) reacts with quinoline-8-carbaldehyde (C9H6NCHO) in the presence of N-donor ligands to give dinuclear rhodium(III) complexes [Rh(μ-Cl)(C9H6NCO)(Nbyl)L]2 (L = pyrid...
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norbornene,complexes
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