Iron-Catalyzed [4C+1N] Cyclization of 4-Acetylenic Ketones with Primary Amines: Synthesis of 5-(Aryl)alkylidene-4,5-dihydropyrroles

Bo Sun,Quan Ma,Yeming Wang,Yuegang Zhao,Peiqiu Liao,Xihe Bi

European Journal of Organic Chemistry（2014）

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摘要

An environmentally friendly route to fully substituted 4,5-dihydropyrroles was developed through the iron-catalyzed [4C+1N] cyclization of 4-acetylenic ketones with primary amines in 1,5-pentanediol.

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关键词

cyclization,synthesis,primary amines,iron-catalyzed

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