A dinuclear [{(p-cym)Ru^IICl}₂(μ-bpytz˙⁻)]⁺ complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene)

Dalton Transactions（2016）

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Abstract

p-Cymene as an ancillary ligand favours the stabilisation of a tetrazine radical bridged in a dinuclear [{(p-cym)RuII}2(μ-bpytz˙−)]+ complex.

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Key words

dinuclear,radical anion,synthesis,p-cymene

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A dinuclear [{(p-cym)RuIICl}2(μ-bpytz˙−)]+ complex bridged by a radical anion: synthesis, spectroelectrochemical, EPR and theoretical investigation (bpytz = 3,6-bis(3,5-dimethylpyrazolyl)1,2,4,5-tetrazine; p-cym = p-cymene)